The Strange World of PTFE and UHMWPE
PTFE, also known as polytetrafluoroethylene or more popularly, Teflon, has become well known for both its high performance, but also for the unfortunate results of sloppy manufacturing. PTFE is a popular type of material with excellent physical characteristics, best among them its extremely high chemical resistance and slippery surface. However, the chemical category of Pressure Sensitive Adhesives (PSA), of which teflon is part, has been tarnished since its birth due to sloppy manufacturing, improper chemical disposal, and terrible handling, resulting in exposure to carcinogens. There has been a dash to reduce the industry’s dependence on PTFE for these legal reasons–and in some states, it is almost outright banned.
However, PTFE is still a crucial material that, while it does require special handling, has many important physical characteristics that can benefit many different industries.
The Invaluable PTFE
PTFE is an invaluable material for seals, because of its “conformability” (low modulus) and viscoelasticity. While it does not recover from deformation as well as an elastomer, its recovery is significantly better than other thermoplastics and meets the needs for seals. Its slick surface makes it excellent for components that will have movement, such as a reversing valve on a heat pump.
The Properties of Teflon
It recovers from deformation, not 100% like an elastomer, but good enough for seals. It is slippery, so a seal with a wiping motion works very well. An example is a reversing valve on heat pumps.
PTFE is typically processed by compression molding and has a high viscosity at melt similar to Jello. It expands by 30% at that melt condition and has surprisingly poor elongation. A 600F block of PTFE with a hole in it, put over a steel pin of close size will crack during cooling. It doesn’t work well with injection molding, tending to deform significantly during the process. On the other hand, compression molding of PTFE is a lot like free sintering, where a compacted powder is placed into a sintering oven to solidify.
A Wide Range of Applications
PTFE is best known for its beneficial ‘stick-slip’ property. While it may hamper control applications, PTFE has little to no difference in static and dynamic friction, making it excellent for pneumatic slip valves, balls, plugs, and butterfly valves, especially in demanding chemical applications.
In addition, powdered PTFE is a common additive for many applications. Here there are fine differences between powders that are made from virgin resin and cryogenically ground in ball mills expensively, and powders that have been irradiated and ground less expensively because the damaged particle is more brittle. There have also been some instances where the irradiated version has led to stress cracking in high concentrations with a few materials. PTFE powder-coated frying pans are the most recognizable application, but this type of coating can also be found across many industrial applications too.
The Poor Man’s Teflon
UHMWPE (ultra-high molecular weight polyethylene) is an equally fascinating material often used in discussion with PTFE. UHMWPE has the appearance and slick surface of an ice skating rink, but with extremely high wear resistance and cut resistance in addition to low friction.
What does ultra-high mean?
But what molecular weight actually constitutes ‘ultra high’? This is a debate that’s gone on for decades. Some manufacturers have argued that either 2 million or 5 million is high enough to fit that description, and many fell into one camp or another depending on the products they were making. For instance, snowmobile manufacturers required the increased impact strength that comes with 5 mil molecular weight, and the twin screw extruders that processed UHMW economically at 2 million molecular weight disagreed with the ram extruders that developed 5 million molecular weight. Then there was the difficulty in measuring the molecular weight. Traditionally, manufacturers used intrinsic viscosity in a hot decalin solution, but it tended to give widely different results due to cross-linking that took place.
Processing UHMWPE
Processing UHMWPE has been mostly limited to hot compression molding, twin screw extrusion, and ram extrusion. However, a very unique method of processing was developed by Crown Plastics where they used a “Formica” continuous compression molding machine that uses a metal conveyor belt between heated platens. They were limited in thickness and width for a long time, but couldn’t be matched when it came to high molecular weight and price.
Properties and Applications
Like PTFE, chemical resistance is remarkable but at a significantly lower temperature. Irradiated, cross-linked parts have the unique characteristic of recovering from dramatically distorted shapes and subsequent recovery.
UHMWPE ends up in the most unique applications thanks to its high molecular weight and unique properties.
- Pulleys for wire rope
- Protective sheets to protect the sides of the ships from the steel wire
- Steel components of fishing gear
- Protective liners for concrete chutes
- Wear surfaces on food processing equipment and snowmobiles
- Bottoms for Skis and Snowboards
- Jigs and fixtures in manufacturing because it is easy to machine to an extent, and readily available as stock shapes.
While UHMWPE is somewhat easy to machine, it does require experience and practice. The problem with machining is that it has a high coefficient of thermal expansion so as the workpiece is being cut with a tool it heats up and changes dimension. High coolant streams help but are not always practical. As an example turning a 2” diameter bearing to a .002” tolerance might take 2-3 trials with an hour or so in between. The second one would be faster because you then know what you need as a hot dimension.
Final Thoughts
These two materials differ dramatically yet so often end up in similar conversations. PTFE has a high specific gravity of 2.1, where UHMW is .96. PTFE is twice to three times the price of UWMW, but with the specific gravity is even more expensive per cubic inch hence the tag of poor man’s Teflon for UHMW. PTFE has a much higher temperature and chemical resistance. Both are slippery and are used as additives in resin blends. UHMW is much more wear, and cut-resistant.